Sanitization and disinfection are the two primary responsibilities of chlorine. Chlorine’s secondary responsibility–or, more accurately, it’s secondary obligation–is oxidation. In terms of residual sanitizer out in the pool water, chlorine is the first line of defense against common recreational water diseases like pseudomonas aeruginosa; bacteria like e. coli; other germs like staphylococcus aureus and giardia; and living organisms like algae.
To help protect people against those nasty waterborne pathogens, there are secondary disinfection systems like UV, but they are a point-of-contact system. In other words, secondary disinfection systems can only affect what they touch, and they only touch what passes through them. Chlorine, on the other hand, is flowing with the water throughout the entire pool and system…it’s everywhere.
You can see this on the chart below. Notice that chlorine residual does not present itself until point A. What happened prior to that? Why did it not start building residual from the start? The answer is metals between 0 and point A. The chart labels it as “Destruction of chlorine residual by reducing compounds.” For more information on the science of chlorination,read this.
2. Non-living organics (bather waste)
Why are we depending on chlorine alone to remove non-living organic waste from the pool? Chlorine is critical to the safety and wellbeing of everyone in the pool because of disinfection…not removing bather waste. But alas, the bather waste (such as sweat, urine, body oils, mucus, lotions, cosmetics, deodorants and hair gels) must be oxidized to get them out. Right?
Wrong. Oxidation is not the most efficient or effective means of removing bather waste from a swimming pool. Try using SimplyPURE enzymes instead. They are strong enough for wastewater; yet safe enough to meet the NSF/ANSI 50 standard. The enzymes flow throughout the entire pool system–alongside chlorine–and devour organic contamination to reduce the burden on chlorine. By using enzymes, chlorine is freed up to sanitize and disinfect…and that’s what we need it for in a pool.
More specifically than non-living organics, however, are nitrogen compounds. Nitrogen compounds combine with chlorine (to create combined chlorine). The breakpoint chlorination process shows this occurring, then the eventual destruction of combined chlorine compounds like monochloramine and dichloramine. Eventually, with enough hypochlorous acid (HOCl) to break it down and convert it to nitrogen trichloride (aka trichloramine), these compounds will off-gas into the air. They then become an air quality problem.
3. Ultraviolet light (direct sunlight)
Direct sunlight breaks down chlorine. Without a stabilizer (cyanuric acid) in the water, as much as 90% of free available chlorine could be destroyed within just two or three hours.
We conducted fairly diligent research for this article. We found plenty of sources indicating that direct sunlight breaks down chlorine and bromine; a fact that is irrefutable it seems. What we were looking for, however, we have not yet found. Does anyone know if UV sanitation systems for pools also break down chlorine? And if so, how much? Is it similar or even more severe than sunlight? We think it must be less severe than sunlight, but we honestly do not know. It would be great if a UV manufacturer could contact us and let us know.
But back to what we know. Direct sunlight breaks down chlorine in a matter of hours. Obviously, broken down chlorine is ineffective at sanitation, so therefore sunlight makes this list. Fortunately for outdoor pools, several decades ago a wonderful discovery was made, called…
4. Cyanuric Acid (chlorine stabilizer)
The more stabilizer you have in your pool, the weaker the chlorine.
Without cyanuric acid (CYA), chlorine would break down in a matter of hours in direct sunlight. Something about the UV rays breaking apart the HOCl and OCl- itself, but the specific chemistry is not important to this conversation. Just know that without cyanuric acid, also known as chlorine stabilizer, outdoor pools need to be constantly replenishing free chlorine. It’s good to have some stabilizer in an outdoor pool.
The key is moderation. The US Centers for Disease Control (CDC) released a mandate for regulating the use of cyanuric acid in commercial swimming pools. The new regulation stipulates CYA levels cannot exceed just 15 parts per million! That can be a real problem for pools that use trichlor.
“Chlorine Lock” from cyanuric acid
Why limit the use of a stabilizer that protects chlorine from sunlight? Because it also weakens chlorine. Pool industry experts disagree and debate whether or not “chlorine lock up” is a real thing. The notion being that CYA prevents a certain amount of chlorine from being used. The numbers we have heard range between 5-10%, but the best article we have found on the topic of chlorine lock is from Service Industry News. Read the article. It’s worth your time. And we quote:
“Richard Falk derived his ratio in part by recognizing that even if the free chlorine is the same, the concentration of hypochlorous acid (effective chlorine) changes when cyanuric acid is introduced at different levels…
…He did this by recognizing hypochlorous acid, HOCl (the killing form of chlorine) is proportional to the ratio of free chlorine to cyanuric acid:
HOCl ♀ FC/CYA
Beginning with Powell’s best guesses on free chlorine values that are effective for a given cyanuric acid concentration, Falk determined that one should have a minimum free chlorine to cyanuric acid ratio of 7.5 percent to prevent algae in traditionally chlorinated pools.
Falk’s ratio has made doing the math to prevent algae incredibly easy.
FC = 7.5% x CYA
For example, if the measured cyanuric acid in a swimming pool is 30, then a pool operator should maintain a minimum free chlorine level of 2.25 ppm.
2.25 ppm FC = 7.5% x 30 ppm CYA
If the cyanuric acid is at 70 ppm, the free chlorine should be maintained at a minimum of 5.25 ppm.
5.25 ppm FC = 7.5% X 70 ppm CYA
So, assuming Falk’s numbers are correct, the factor of 7.5% is an important one to understand. If your pool has 100ppm cyanuric acid, you basically don’t have free chlorine until you exceed 7.5ppm chlorine. That’s your new baseline. Crazy, right?
5. More Alkaline pH
The higher the pH, the lower the concentration of HOCl in free chlorine readings. The weaker form of chlorine, hypochlorite ion (OCl-) increases and surpasses HOCl around 7.5 pH.
Let’s not confuse the words alkaline with alkalinity. It happens often in the pool business, and we get asked about the difference between pH & alkalinity all the time. When we say more alkaline pH, we mean higher pH. As you can see from the chart above, pH has a direct impact on the dissociation of H+ from hypochlorous acid in the pool. Hypochlorous acid (HOCl) is the strong, killing form of chlorine We need it in the water! The higher the pH, the less of it there is, as it is replaced by the weaker chlorine, the hypochlorite ion (OCl-). So yes, more alkaline pH can weaken chlorine.
Do you know what else can weaken chlorine via dissociation of the H+?
Yes, phosphates weaken chlorine too. Much like more alkaline pH levels, phosphates pull hydrogen away from hypochlorous acid–they dissociate it. Phosphates are a hot topic in swimming pools, and we have another article that dives more in depth about them here. Just know that eliminating phosphates from your pool can remove another factor that can weaken chlorine. Below is an educational video about how phosphates affect chlorine, created by our parent brand, Orenda. We hope this article was helpful for you. Contact us if you have other topics you would like us to cover in our blog!
https://naturalpoolproducts.com/wp-content/uploads/2017/08/weakchlorine.png315560wave maker/wp-content/uploads/2017/05/Natural-Pool-Products-Logo.pngwave maker2017-08-05 18:29:472019-04-11 19:30:59How to weaken chlorine in a swimming pool